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Abstract The North American craton interior preserves a >1 Ga history of near surface processes that inform ongoing debates regarding timing and drivers of continental‐scale deformation and erosion associated with far‐field orogenesis. We tested various models of structural inversion on a major segment of the Midcontinent Rift along the Douglas Fault in northern Wisconsin, which accommodated ≳10 km of total vertical displacement. U‐Pb detrital zircon and vein calcite Δ₄₇/U‐Pb thermochronometry from the hanging wall constrain the majority of uplift (≳8.5 km) and deformation to 1052–1036 Ma during the Ottawan phase of the Grenvillian orogeny. Combined U‐Pb zircon dates, Δ₄₇/U‐Pb calcite thermochronometry, and field data that document syn‐ to early post‐depositional deformation in the footwall constrain a second stage of uplift (1–1.5 km) ca. 995–980 Ma during the Rigolet phase of the Grenvillian orogeny. A minor phase of Appalachian far‐field orogenesis is associated with minimal thrust reactivation. Our combined analyses identified the 995–980 Ma Bayfield Group as a Grenvillian foreland basin with an original thickness 0.5–2 km greater than currently preserved. By quantifying flexural loading and other subsidence mechanisms along the Douglas Fault, we identify dynamic subsidence as a mechanism that could be consistent with the development of late‐Grenvillian transcontinental fluvial systems. Minimal post‐Grenvillian erosion (0.5–2 km) in this part of the craton interior has preserved the Bayfield Group and equivalent successions, limiting the magnitude of regional erosion that can be attributed to Neoproterozoic glaciation. 

Southwestern North America is currently experiencing a multidecadal megadrought, with severe consequences for water resources. However, significant uncertainty remains about 21st century precipitation changes in this semi-arid region. Paleoclimatic records are essential for both contextualizing current change, and for helping constrain the sensitivity of regional hydroclimate to large-scale global climate. In this paper, we present a new 2.8 Ma to present compound-specific isotopic record from Clayton Valley, the site of a long-lived paleolake in the southern Great Basin. Hydrogen and carbon isotopes from terrestrial plant leaf waxes provide evidence of past shifts in rainfall seasonality as well as ecosystem structure, and help contextualize the formation of this lithium-rich lacustrine basin. Our results suggest that regional hydroclimates underwent a substantial reorganization at the Plio-Pleistocene boundary, especially between 2.6 and 2.0 Ma. In this interval, a reduced latitudinal temperature gradient in the North Pacific likely resulted in a northward shift in storm tracks, and a reduction in winter rainfall over the southern Great Basin. This occurred against a background of increased summer rainfall and a greater accumulation of lithium in the lake basin. Our interpretation is corroborated by a compilation of Plio-Pleistocene north Pacific sea surface temperature records, as well as an isotope-enabled model simulation. Overall, these results suggest that past shifts in rainfall seasonality helped set the stage for the development and dessication of lithium-rich lacustrine deposits. 

The stable isotopic composition of soil-formed carbonate, and bulk geochemistry of preserved soil matrix, can provide regionally constrained records of hydroclimatic change throughout deep-time. The SK cores, spanning over 10 km of sediment drilled from the Songliao Basin in Northeast China, represent near continuous terrestrial deposition across the late Jurassic to early Paleogene. In this study we analyze SK-1n paleosol core samples spanning late Maastrichtian to early Danian to interpret the regional hydroclimate response to global climate change, concurrent with Deccan Traps volcanism and the Chicxulub impact. Building on numerous paleosol carbonate datasets from the Sifangtai and Mingshui formations, we present ~40 new carbonate clumped isotope measurements at ca. 10 – 20 kyr resolution between 66.3 to 65.5 Ma. We produce a new kernel-smoothed temperature record and estimate the δ18O of soil porewater (δ18Opw), and δ13C of soil CO2 (δ13Cs) from new and previously published datasets. Molecular weathering ratios, derived from bulk geochemistry, are used to reconstruct weathering (CIA-K), clay formation (Al/Si), soil drainage (Ba/Sr), and calculate mean annual precipitation (MAP) via established transfer functions. Preliminary results suggest elevated K-Pg boundary temperatures, averaging ~30 °C, that decline by ~10 °C over the following 500 kyr. Post-impact cooling may contribute to a negative δ18Ocarb excursion (-2.5‰) at ~65.8 Ma. Further, stable subhumid MAP (~1100 mm/yr) across the dataset suggests negligible amount effect influence. Mean δ18Opw (-6.9‰) is largely stable, and does not reflect regional monsoon seasonality. Instead, stable δ18Opw indicates a consistent moisture source, a potential persistent seasonal bias in carbonate formation. Binning all compiled δ18Opw by soil profile depth reveals statistically significant enrichment in the upper 60 cm of soil profiles, and accounts for variability in the δ18Opw (σ = 1.16‰). Soil respiration, modeled from δ13Cs, increases from ca. 700 to 2000 gC/m2/year across the K-Pg boundary, indicating increased productivity despite declining pCO2 and available phosphorus. Future work will expand the temporal range of isotopic measurements (~72 to 65 Ma) and contextualize our latest Cretaceous results within a spatial framework across Asia. 

Silicate weathering and organic carbon (OC) burial in soil regulate atmospheric CO2, but their influence on each other remains unclear. Generally, OC oxidation can generate acids that drive silicate weathering, yet clay minerals that form during weathering can protect OC and limit oxidation. This poses a conundrum where clay formation and OC preservation either compete or cooperate. Debate remains about their relative contributions because quantitative tools to simultaneously probe these processes are lacking while those that exist are often not measured in concert. Here we demonstrate that Li isotope ratios of sediment, commonly used to trace clay formation, can help constrain OC cycling. Measurements of river suspended sediment from two watersheds of varying physiography and analysis of published data from Hawaii soil profiles show negative correlations between solid-phase d7Li values and OC content, indicating the association of clay mineral formation with OC accumulation. Yet, the localities differ in their ranges of d7Li values and OC contents, which we interpret with a model of soil formation. We find that temporal trends of Li isotopes and OC are most sensitive to mineral dissolution/clay formation rates, where higher rates yield greater OC stocks and lower d7Li values. Whereas OC-enhanced dissolution primarily dictates turnover times of OC and silicate minerals, clay protection distinctly modifies soil formation pathways and is likely required to explain the range of observations. These findings underscore clay mineral formation, driven primarily by bedrock chemistry and secondarily by climate, as a principal modulator of weathering fluxes and OC accumulation in soil. 

Photorespiration can limit gross primary productivity in terrestrial plants. The rate of photorespiration relative to carbon fixation increases with temperature and decreases with atmospheric [CO₂]. However, the extent to which this rate varies in the environment is unclear. Here, we introduce a proxy for relative photorespiration rate based on the clumped isotopic composition of methoxyl groups (R–O–CH₃) in wood. Most methoxyl C–H bonds are formed either during photorespiration or the Calvin cycle and thus their isotopic composition may be sensitive to the mixing ratio of these pathways. In water-replete growing conditions, we find that the abundance of the clumped isotopologue¹³CH₂D correlates with temperature (18–28 °C) and atmospheric [CO₂] (280–1000 ppm), consistent with a common dependence on relative photorespiration rate. When applied to a global dataset of wood, we observe global trends of isotopic clumping with climate and water availability. Clumped isotopic compositions are similar across environments with temperatures below ~18 °C. Above ~18 °C, clumped isotopic compositions in water-limited and water-replete trees increasingly diverge. We propose that trees from hotter climates photorespire substantially more than trees from cooler climates. How increased photorespiration is managed depends on water availability: water-replete trees export more photorespiratory metabolites to lignin whereas water-limited trees either export fewer overall or direct more to other sinks that mitigate water stress. These disparate trends indicate contrasting responses of photorespiration rate (and thus gross primary productivity) to a future high-[CO₂] world. This work enables reconstructing photorespiration rates in the geologic past using fossil wood. 

Abstract Ice cores and offshore sedimentary records demonstrate enhanced ice loss along Antarctic coastal margins during millennial-scale warm intervals within the last glacial termination. However, the distal location and short temporal coverage of these records leads to uncertainty in both the spatial footprint of ice loss, and whether millennial-scale ice response occurs outside of glacial terminations. Here we present a >100kyr archive of periodic transitions in subglacial precipitate mineralogy that are synchronous with Late Pleistocene millennial-scale climate cycles. Geochemical and geochronologic data provide evidence for opal formation during cold periods via cryoconcentration of subglacial brine, and calcite formation during warm periods through the addition of subglacial meltwater originating from the ice sheet interior. These freeze-flush cycles represent cyclic changes in subglacial hydrologic-connectivity driven by ice sheet velocity fluctuations. Our findings imply that oscillating Southern Ocean temperatures drive a dynamic response in the Antarctic ice sheet on millennial timescales, regardless of the background climate state. 

Abstract High‐latitude glacierized coastal catchments of the Gulf of Alaska (GoA) are undergoing rapid hydrologic changes in response to climate change and glacial recession. These catchments deliver important nutrients in the form of both inorganic and organic matter to the nearshore marine environment, yet are relatively understudied with respect to characterization of the sediment and solute generation processes and total yields. Using multiple linear regression informed by Bayesian Information Criterion analysis we empirically demonstrate how watershed characteristics affect suspended sediment and solute generation as represented by concentration‐discharge relationships. We find that watershed mean slope and relief control solute generation and that solute yields are influenced most by glacier coverage. We contribute a new flux and concentration‐discharge based conceptualization for understanding solute cycles across a hydroclimatic gradient of GoA watersheds that can be used to better understand future watershed responses to rapid hydrologic change.